ISO-6923 Paints and varnishes - Determination of monomeric diisocyanate content in coating materials and similar products using high performance liquid chromatography with ultraviolet detection (HPLC-UV)

ISO-6923 - 1ST EDITION - CURRENT


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This document specifies a method for the quantitative determination of monomeric diisocyanate content in coating materials, adhesives and other liquid or pasty materials.

This method is suitable for the quantification of the following monomeric diisocyanates: methylene diphenyl diisocyanate (MDI, 2,4.-MDI and 4,4.-MDI), toluene diisocyanate (TDI, 2,6-TDI, 2,4-TDI), (cis/trans) isophorone diisocyanate (IPDI) and hexamethylene diisocyanate (HDI,1,6-HDI) in various matrices for concentrations ranging from 0,01 % to 2,0 % mass fraction. For higher concentrations, a suitable dilution before the derivatization with p-nitrobenzyl-N-propylamine (PNBPA) is performed. The measurements are carried out using ultra high performance liquid chromatography (UHPLC) with a multiple wavelength detector.

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Document Number

ISO 6923:2023

Revision Level

1ST EDITION

Status

Current

Publication Date

Sept. 1, 2023

Committee Number

ISO/TC 35/SC 16